By H F W Taylor
Bargains with the chemistry of the crucial silicate and aluminate cements utilized in development and civil engineering. Aimed basically at these whose heritage is in chemistry, fabrics technology or comparable disciplines, the e-book emphasizes the underlying technology instead of sensible purposes.
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Extra resources for Cement Chemistry
0 6 ~ 0 . 0 0 . 0 1. 0 1 3 . 's data. is 3326 kgm-3, and that for pure y-C2S, based on those of Udagnwa rt (11. (U4), is 2960 kg n ~ - ~ . 7 17. 654 (R4). 003 (01). Ono et uI. (01) and Yamaguchi and Takagi (Y 1) give further data on the optical properties of clinker belites. Guinier and Regourd (GI) summarized the thermal behaviour of C2S polymorphs. due respectively to the P -+ a', and a', -, a transitions; with y-C,S, the 693•‹Cendotherm is replaced by a broad one beginning at about 748•‹C due to the transition to a',.
This chapter deals with these equilibria and with the phases to which they relate, with the exception of the major clinker phases, whicti wkre described in Chapter I. Some anhydrous phases primarily of interest in relation to other types of cement are also considered here. Principles underlying the preparation of anhydrous silicate, aluminate and other hightemperature phases are outlined. 1 The CaO-SiO, system Fig. 1 shows the phase diagram. For clarity, the polymorphism of C,S and the distinction between a',- and a',-C,S are omitted.
If a liquid having a composition somewhat on the CaO-rich side of the boundary between the CaO and C3A primary phase fields (Fig. 5) is cooled calcium oxide is initially deposited and the liquid composition moves away from CaO and towards that boundary. When the latter is reached, and assuming that equilibrium were to be maintained, calcium oxide would redissolve, C3A would be deposited, and the liquid composition would move along the boundary. In reality, the C3A quickly surrounds the particles of calcium oxide, which thus form a protected phase, effectively removed from the system.
Cement Chemistry by H F W Taylor