By Mary Fieser

ISBN-10: 047125875X

ISBN-13: 9780471258759

The good revered and ever well known Fieser and Fieser sequence on reagents for natural synthesis offers concise descriptions, stable structural formulation and chosen examples of purposes. * offers references to new reagents in addition to to reagents integrated in earlier volumes * hundreds of thousands of entries summary an important info on prevalent and new reagents, together with guidance, makes use of, assets of provide, serious reviews, references and extra * Reagents are thought of in alphabetical order by way of universal utilization names.

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Example text

The principal objection to free-radical halogenation is that it is not a useful synthetic reaction. But useful reactions such as nucleophilic substitution and additions to alkenes are complicated by participation of the solvent and other effects. Gas-phase free-radical halogenation allows a clearer treatment of kinetics and thermodynamics, as long as its disadvantages as a synthetic reaction are discussed and students are aware of the limitations. Organic Synthesis Organic synthesis is stressed throughout this book, with progressive discussions of the process involved in developing a synthesis.

Hydrogen, for example, needs a second electron to achieve the noble-gas configuration of helium. If two hydrogen atoms come together and form a bond, they “share” their two electrons, and each atom has two electrons in its valence shell. H ϩ H H H each H shares two electrons (He configuration) We will study covalent bonding in more detail in Chapter 2. One way to symbolize the bonding in a covalent molecule is to use Lewis structures. In a Lewis structure, each valence electron is symbolized by a dot.

Most of the millions of carbon compounds are classified as organic, however. We ourselves are composed largely of organic molecules, and we are nourished by the organic compounds in our food. The proteins in our skin, the lipids in our cell membranes, the glycogen in our livers, and the DNA in the nuclei of our cells are all organic compounds. Our bodies are also regulated and defended by complex organic compounds. nicotine carmine vitamin C OH CH2OH N N CH3 HCOH H HO O morphine O glucose N CH3 COOH O OH OH HO OH O OH O H OH Four examples of organic compounds in living organisms.

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Fieser's Reagents for Organic Synthesis Volume 1 by Mary Fieser

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