By Jan Schwarzbauer, Branimir Jovančićević

ISBN-10: 3319115529

ISBN-13: 9783319115528

ISBN-10: 3319119389

ISBN-13: 9783319119380

The first quantity during this new textual content publication sequence covers comprehensively suitable points regarding the looks and characterisation of fossil subject within the geosphere akin to kerogen, oil, shales and coals. As natural geochemistry is a contemporary clinical topic characterised by way of a excessive transdisciplinarity and found on the fringe of chemistry, environmental sciences, geology and biology, there in actual fact is a necessity for a versatile provide of acceptable educational instructing fabric on an undergraduat point addressed to the diversity of scholars coming initially from various research disciplines. For any such versatile utilization this textbook sequence' includes assorted volumes with transparent outlined elements and with plausible length.

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Extra resources for Fossil Matter in the Geosphere

Example text

5 Molecular structure of tetracyclic terpanes By analysis of tricyclic terpanes in a number of geological samples, it was concluded that organic matter from saline lacustrine environment and marine organic matter usually contain a greater amount of tricyclic terpanes, where C23 terpane is most abundant. In the organic matter of terrestrial origin, these polycyclic hydrocarbons are much less present, and the most abundant among them is C20 tricyclic terpane. Regardless of the origin, among the tricyclic terpanes, the least abundant are C22 and C27 terpanes.

Therefore, along with examining the origin and structural and stereochemical changes of steranes, tests aimed at detecting biological precursors, and transformational paths of tri-, tetra- and pentacyclic terpanes are also presented. In the alkane fractions of recent sediments tricyclic terpanes are present in traces, or are not present at all. The largest amount of these hydrocarbons is incorporated into kerogen or is in the form of polar fractions of bitumens, resins and asphaltenes, from which it is released during thermal degradation of the sediment.

N-Alkanes and isoprenoid alkanes, pristane and phytane, are analyzed also by gas chromatography—mass spectrometry. 4, n-alkanes are identified using ions m/z 71, 85 or 99 (usually m/z 71), and isoprenoids are identified using m/z 113, 183 or 197 (usually m/z 183). 13). Sterane is usually identified using ion m/z 217, and triterpane using ion m/z 191. 6. Fig. 14 Example of sterane distribution in an ancient sediment as illustrated by the m/z 217 ion chromatogram. 5) Fig. 15 Example of terpane distribution in an ancient sediment as illustrated by the m/z191 ion chromatogram.

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Fossil Matter in the Geosphere by Jan Schwarzbauer, Branimir Jovančićević


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