By Charles Donald Holland; Rayford G Anthony
Basics Of Chemical response Engineering, by means of Holland, Charles D. And Rayford
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Extra resources for Fundamentals of chemical reaction engineering
Note that, if D is the desired point of operation, the reactor temperature would have to rise to reach that point. This means, the temperature would need to move through the lower steady state point (“B”) as well as the unstable steady state point (“C”). e. not adding or withdrawing heat). One straightforward way of achieving the temperatures associated with Point D would be to use a burst of additional heat. Remember that all this was developed assuming a simple reaction rate expression, rA = k CA.
It may also be noted that the shape of the material balance remains unchanged for exothermic and endothermic reactions. 5 The material and energy balance lines for a non-isothermal CSTR. The intersections indicate the position of the simultaneous solution. The treatment for a simple 1st order irreversible reaction is thus relatively easy. It would get considerably more complicated even for the simple reversible reaction A R B . In any case, the basic design problem consists of finding “the most desirable” intersection of the mass and energy balances.
E. the equation nT H ¦ ni H fi ) , the mass balance for a CSTR (Eq. 8) may now be written as ¦ ni0 H fi ( T0 ) ¦ ni H fi ( T ) Energy flow in Energy flow out 0 , Q Heat exchange (Eq. 12) Accumulation (nil at steady state) where the subscript ‘0’ in Eq. 12 refers to the reactor inlet conditions. In a “non-isothermal CSTR,” the temperature is uniform everywhere within the reaction zone. Non-isothermal behaviour in a CSTR refers to differences between the feed temperature (T0) and the reaction temperature (T), the heat absorbed or released by the chemical reaction and to heat exchange between the reactor and the surroundings.
Fundamentals of chemical reaction engineering by Charles Donald Holland; Rayford G Anthony