By Xiaoyao Tan, Kang Li
Membrane reactors mix membrane services reminiscent of separation, reactant distribution, and catalyst help with chemical reactions in one unit. some great benefits of this method comprise more desirable conversion, elevated yield, and selectivity, in addition to a extra compact and cost-effect layout of reactor process. for this reason, membrane reactors are an efficient path towards chemical procedure intensification.
This e-book covers every kind of porous membrane reactors, together with ceramic, silica, carbon, zeolite, and dense steel reactors reminiscent of Pd or Pd-alloy, oxygen ion-conducting, and proton-conducting ceramics. for every kind of membrane reactor, the membrane shipping rules, membrane fabrication, configuration and operation of membrane reactors, and their present and power functions are defined comprehensively. A precis of the severe concerns and hurdles for every membrane response strategy can also be supplied, with the purpose of encouraging profitable advertisement applications.
The viewers for Inorganic Membrane Reactors contains complicated scholars, commercial and educational researchers, and engineers with an curiosity in membrane reactors.
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Extra info for Inorganic Membrane Reactors: Fundamentals and Applications
Reproduced from . With permission from Elsevier. 20 Fundamentals of Membrane Reactors hotocatalytic membranes prepared by the sol-gel process are used p for the continuous degradation of volatile organic compounds (VOCs) in water . Most perovskite membranes for oxygen permeation also exhibit good catalytic activity toward the oxidation of hydrocarbons . ” In most cases, catalytic membranes do not need to be perm-selective but are required to be highly active for the reactions considered and to have a sufficiently low overall permeability so that they are operated in the diffusion-controlling regime.
Separation and Purification Technology, 25, 151–159. J. and Cot, L. , Amsterdam.  Coronas, J. and Santamaria, J. (1999) Catalytic reactors based on porous ceramic membranes. Catalysis Today, 51, 377–389. , Farrusseng, D. and Guizard, C. (2001) Porous ceramic membranes for catalytic reactors – overview and new ideas. Journal of Membrane Science, 181, 3–20. H. J. (1991) Reaction of methanol over catalytically active alumina membranes. Applied Catalysis, 74, 205–222. , Yoshioka, T. and Asaeda, M.
The main problem with sol-gel-derived membranes is the thermal and hydrothermal instability (pore growth, grain coarsening, phase transition, defect development) above 400–500°C. ) is required [11, 12]. The challenges for sol-gel-derived porous membranes involve the preparation of thin perm-selective films and high-quality but low-cost underlying macroporous supports. 3 Chemical Vapor Deposition Method The CVD method is a technique to produce microporous membranes by deposition of a solid inside the pores of mesoporous membranes, thus reducing the pore size through chemical reactions in a gaseous medium at an elevated temperature.
Inorganic Membrane Reactors: Fundamentals and Applications by Xiaoyao Tan, Kang Li