By Hisashi Yamamoto, Koichiro Oshima

ISBN-10: 3527305084

ISBN-13: 9783527305087

This is often the 1st guide to hide intimately all features of this interesting box of chemistry. In convenient volumes, readers will immediately locate theformation they want, in actual fact dependent in response to the person parts of the periodic desk, hitherto simply available after a lot time-consuming learn. briefly, a needs to for each natural chemist.Описание: A two-volume set that gives details dependent in accordance with the person metals usually teams.

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R. ; Wiley, New York, 1987, Vol. 4, p. 1. Wakefield, B. , Organolithium Methods; Academic Press, London, 1988. , in Organometallics in Synthesis; Schlosser, M. ; Wiley, New York, 1994, p 1. , Jain, D. ; Schleyer, P. v. R. ; New York, Wiley, 1995. , in Organometallics in Synthesis A Manual; Schlosser, M. ; Wiley, Baffins Lane, 2002, p. 1. , Organolithiums: Selectivity for Synthesis, Pergamon, Amsterdam, 2002. , Marek, I. , The Chemistry of Organolithium Compounds; Wiley, New York, 2003. , J. Org.

E. , J. Am. Chem. Soc. 1968, 90, 3245. , Kerrick, S. , J. Am. Chem. Soc. 1994, 116, 3231. , Chem. Eur. J. 1999, 5, 3459. , Tetrahedron Lett. 1999, 40, 6809. , Tetrahedron Lett. 2000, 41, 6121. , J. Am. Chem. Soc. 1984, 106, 2440. , J. Am. Chem. Soc. 1996, 118, 7634. Larson, G. , Rappoport, Z. ; Wiley, Chichester, 1989, p. 787. Ager, D. , Org. React. 1990, 38, 1. Huryn, D. , in Comprehensive Organic Synthesis; Trost, B. , Fleming, I. ; Pergamon, Oxford, 1991, Vol. 2. Still, W. , Tetrahedron Lett.

1 Nucleophilic Fluorination Because of the low nucleophilicity of the fluoride ion, nucleophilic fluorination is not very easy. The reaction conditions and the reagent are, however, sufficiently mild to produce unstable compounds. 4). The N-haloimines obtained are potentially unstable compounds [7]. 4 Although direct nucleophilic addition is limited because of the low nucleophilicity of the fluoride ion, a palladium-catalyzed reaction enables the weak nucleophile to participate the addition reaction.

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Main Group Metals in Organic Synthesis by Hisashi Yamamoto, Koichiro Oshima

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